Chembox verifiedrevid 476996956 verifiedrevid Name Borontrifluoride ImageFileL1 Borontrifluoride 2D dimensions.png ImageSizeL1 130px ImageNameL1 Borontrifluoride in 2D ImageFileR1 Borontrifluoride 3D vdW.png ImageSizeR1 120px ImageNameR1 Borontrifluoride in 3D Section1 Chembox Identifiers ChemSpiderID ... List of UN Numbers 2601 to 2700 2604 . br Borontrifluoride dimethyl etherate List of UN Numbers 2901 to 3000 2965 . br Borontrifluoride dihydrate List of UN Numbers 2801 to 2900 2851 . Section2 Chembox ... C Reference ref CLP Regulation index 005 001 00 X page 341 ref ref PGCH ref id 0062 name Borontrifluoride ... br Boron tribromide br Boron triiodide br Boron monofluoride Borontrifluoride is the chemical ... p orbitals on fluorine atoms. ref name greenwood Image Borontrifluoride pi bonding 2D.png 100px Borontrifluoride pi bonding diagram Synthesis and handling BF sub 3 sub is manufactured by the reaction ... Diego year 2001 isbn 0 12 352651 5 ref Approximately 2300 4500 tonnes of borontrifluoride are produced ... BF sub 3 sub nitrogen N sub 2 sub Anhydrous borontrifluoride has a normal boiling temperature of &minus ... Handbook publisher McGraw Hill year 1999 page 25 ref Borontrifluoride is corrosive. Suitable metals for equipment handling borontrifluoride include stainless steel , monel , and hastelloy . In presence ... based, as borontrifluoride reacts with the hydrocarbon based ones. ref cite web publisher ... Borontrifluoride ref Reactions Unlike the aluminium and gallium trihalides, the boron trihalides ... halides cannot be obtained in pure form. Borontrifluoride is a versatile Lewis acid that forms ... with diethyl ether , borontrifluoride diethyl etherate or just borontrifluoride etherate BF sub ..., T. Murray, J. S. Politzer, P. title A Computational Analysis of the Bonding in BoronTrifluoride ... 32 issue 12 pages 2622 2625 doi 10.1021 ic00064a008 ref Hydrolysis Borontrifluoride reacts with water ... adduct, H sub 2 sub O BF sub 3 sub , which then loses HF that gives fluoboric acid with borontrifluoride ... more details
Trifluoride s are compounds having three fluorines per formula unit. Many metals form trifluorides, such as iron, the rare earth element s, and the metals in the aluminium and scandium columns of the periodic table. No trifluoride is soluble in water, but several are soluble in other solvents. ref cite book page 51 title The Rare Earth Trifluorides Introduction to materials science of multicomponent metal fluoride crystals author Sobolev, Boris Petrovich publisher Institut d Estudis Catalans year 2001 isbn 847283610X ref List of trifluorides Aluminium trifluoride Antimony trifluoride , SbF sub 3 sub , sometimes called Swart s reagent Arsenic trifluoride , AsF sub 3 sub Bismuth trifluoride , BiF sub 3 sub Borontrifluoride , BF sub 3 sub , a pungent colourless toxic gas Bromotrifluoromethane , carbon monobromide trifluoride Bromine trifluoride , BrF sub 3 sub Chlorine trifluoride , ClF sub 3 sub Chromium trifluoride Cobalt trifluoride Diethylaminosulfur trifluoride DAST is the organosulfur compound with the formula Et sub 2 sub NSF sub 3 sub Fluoroform , methyl trifluoride Gallium trifluoride Gold trifluoride Indium trifluoride Iodine trifluoride , IF sub 3 sub , a yellow solid which decomposes above 28 C Iron trifluoride Lanthanum trifluoride Manganese trifluoride Nitrogen trifluoride , NF sub 3 sub , a colorless, toxic, odourless, nonflammable gas Palladium II,IV fluoride Phosphorus trifluoride , PF sub 3 sub , a colorless and odorless gas Plutonium trifluoride Rhodium trifluoride Samarium trifluoride Scandium trifluoride Thiazyl trifluoride , NSF sub 3 sub , a stable, colourless gas, and important precursor to other sulfur nitrogen fluorine compounds Thiophosphoryl trifluoride PSF sub 3 sub colourless gas spontaneously burning with a very cool flame Titanium trifluoride Uranium trifluoride Vanadium trifluoride Vanadium V oxytrifluoride Ytterbium trifluoride Yttrium trifluoride References Reflist Category Chemical compounds ... more details
Borontrifluoride pi bonding 2D.png 100px thumb BorontrifluorideBoron III trifluoride structure ..., fluoride F sup sup and borontrifluoride BF sub 3 sub combined to give the tetrafluoroborate anion, BF sub 4 sub sup sup . Borontrifluoride is used in the petrochemical industry as a catalyst ... ether adduct of borontrifluoride DME BF sub 3 sub and column chromatography of borates are being ... carbide product Infobox boronBoron IPAc en icon b r n is the chemical element with atomic number 5 and the chemical symbol B . The atomic mass is 10.81. Boron is a metalloid . Because boron is produced entirely by cosmic ray spallation and not by stellar nucleosynthesis , ref cite ... Boron come from? accessdate 2011 12 04 ref it is a low abundance element in both the solar system and the Earth s crust. However, boron is concentrated on Earth by the water solubility of its more common ... ore s, such as borax and kernite . Chemically uncombined boron is not found naturally on Earth. Industrially, very pure boron is produced with difficulty, as boron tends to form refractory materials containing small amounts of carbon or other elements. Several allotropy allotropes of boron exist amorphous boron is a brown powder and crystalline boron is black, extremely hard about 9.5 on Mohs Scale Mohs scale , and a poor conductor at room temperature. Elemental boron is used as a dopant in the semiconductor industry . The major industrial scale uses of boron compounds are in sodium perborate bleaches, and the borax component of fiberglass insulation. Boron polymers and ceramics play specialized roles as high strength lightweight structural and refractory materials. Boron compounds are used in silica based glasses and ceramics to give them resistance to thermal shock . Boron containing reagents ... boron containing organic pharmaceuticals are used, or are in study. Natural boron is composed of two stable isotopes, one of which boron 10 has a number of uses as a neutron capturing agent. In biology ... more details
chembox verifiedrevid 438585399 ImageFileL1 Boron triiodide.svg ImageSizeL1 120px ImageFileR1 Boron triiodide 3D vdW.png ImageSizeR1 120px IUPACName triiodoborane OtherNames Reference ref RubberBible86th ref Section1 Chembox Identifiers ChemSpiderID Ref chemspidercite correct chemspider ChemSpiderID 75378 InChI 1 BI3 c2 1 3 4 InChIKey YMEKEHSRPZAOGO UHFFFAOYAR StdInChI Ref stdinchicite correct chemspider StdInChI 1S BI3 c2 1 3 4 StdInChIKey Ref stdinchicite correct chemspider StdInChIKey YMEKEHSRPZAOGO UHFFFAOYSA N CASNo Ref cascite correct ?? CASNo 13517 10 7 PubChem 83546 SMILES IB I I Section2 Chembox Properties Formula BI sub 3 sub MolarMass 391.52 g mol Appearance crystalline solid Density 3.35 g cm sup 3 sup 50 C MeltingPtC 49.9 BoilingPtC 210 Solubility reacts Section3 Chembox Hazards MainHazards FlashPt 18 C Autoignition Section8 Chembox Related OtherCpds Borontrifluoride br Boron trichloride br Boron tribromide Boron triiodide is a chemical compound of boron and iodine with chemical formula BI sub 3 sub . It has a trigonal planar molecular geometry . It is a crystalline solid, which reacts vigorously with water to from boric acid http www.sciencemadness.org talk files.php?pid 110072&aid 4171 . Its dielectric constant is 5.38 and its heat of vaporization is 40.5 kJ mol. References Reflist External links http www.chemexper.net specification e chemicals supplier cas Boron 20triiodide.asp MSDS Iodides Boron compounds Category Boron compounds Category Iodides Category Boron halides de Bortriiodid el fa nl Boortrijodide ja pl Jodek boru ru zh ... more details
chembox ImageFile Kristallstruktur Yttrium III fluorid.png ImageSize ImageName Bismuth trifluoride IUPACName Bismuth III fluoride OtherNames Bismuth trifluoride Section1 Chembox Identifiers ChemSpiderID 21172751 InChI 1 Bi.3FH.3H h 3 1H q 3 p 3 rBiH3.3FH h1H3 3 1H q 3 p 3 InChIKey GRQDKISMHISLGB IZWAAGQTAY CASNo 7787 61 3 PubChem 82233 SMILES F . F . F . BiH3 3 Section2 Chembox Properties Formula BiF sub 3 sub MolarMass 265.97550 g mol Appearance grey white powder Density 5.32 g cm sup 3 sup ref name alfa aesar http www.alfa.com content msds english 11844.pdf ref MeltingPt 649 C ref name Greenwood Greenwood&Earnshaw ref BoilingPt Solubility Insoluble in water ref name alfa aesar Section3 Chembox Structure CrystalStruct Orthorhombic , Pearson symbol oP16 , SpaceGroup Pnma, No. 62 phase Section7 Chembox Hazards MainHazards Irritant RPhrases R36 38 SPhrases S26 FlashPt Autoignition Bismuth trifluoride is a chemical compound of bismuth and fluorine . The chemical formula is BiF sub 3 sub . It is a grey white powder melting at 649 C. Synthesis Bismuth trifluoride can be prepared by reacting bismuth III oxide with hydrofluoric acid ref name Greenwood Bi sub 2 sub O sub 3 sub 6 HF BiF sub 3 sub 3 H sub 2 sub O Structure BiF sub 3 sub has a cubic crystalline structure Pearson symbol cF16, space group Fm 3m, No. 225 . BiF sub 3 sub has the yttrium III fluoride YF sub 3 sub structure where the bismuth atom has distorted 9 coordination, tricapped trigonal prism. ref name Wells Wells A.F. 1984 Structural Inorganic Chemistry 5th edition Oxford Science Publications ISBN 0 19 855370 6 ref This structure is generally considered to be ionic, and contrasts with fluorides of the lighter members of group 5, phosphorus trifluoride , PF sub 3 sub , arsenic trifluoride , AsF sub 3 sub and antimony trifluoride , SbF sub 3 sub , where MX sub 3 sub molecular units are present in the solid. ref name Wells References reflist Bismuth compounds Category Bismuth compounds Category Fluorides ... more details
chembox verifiedrevid 446241217 ImageFile Bromine trifluoride chemical structure.png ImageSize 120px ImageName Structural formula, showing bond lengths and angles ImageFile1 Bromine trifluoride 3D vdW.png ImageSize1 150px ImageName1 Bromine Trifluoride Section2 Chembox Properties Formula BrF sub 3 sub MolarMass 136.90 g mol Appearance straw coloured liquid br hygroscopic Density 2.803 g cm sup 3 sup ref RubberBible87th ref Solubility decomposes Solvent sulfuric acid SolubleOther soluble MeltingPt 8.77 C BoilingPt 125.72 C Viscosity Section3 Chembox Structure MolShape T shaped C sub 2v sub Dipole 1.19 Debye D Section7 Chembox Hazards ExternalMSDS EUClass not listed NFPA H 3 NFPA F NFPA R 3 NFPA O OX Section8 Chembox Related OtherAnions Bromine monochloride OtherCations Chlorine trifluoride br Iodine trifluoride OtherCpds Bromine monofluoride br Bromine pentafluoride Bromine trifluoride is an interhalogen compound with the formula BrF sub 3 sub . This toxic, colourless, and corrosive liquid is soluble in sulfuric acid but explodes on contact with water and organic compounds. It is a powerful fluorinating agent and an ionizing inorganic solvent. It is used to produce uranium hexafluoride UF sub 6 sub in the processing and reprocessing of nuclear fuel. ref name Greenwood Greenwood&Earnshaw ref Synthesis Bromine trifluoride was first described by Paul Lebeau in 1906, who obtained the material by the reaction of bromine with fluorine at 20 ° C ref name lebeau cite journal author Lebeau P. title The effect of fluorine on chloride and on bromine journal Annales de Chimie et ... of bromine monofluoride also gives bromine trifluoride ref name simons cite journal author Simons JH title Bromine III Fluoride Bromine Trifluoride journal Inorganic Synthesis year 1950 ... chlorine trifluoride ClF sub 3 sub and iodine trifluoride IF sub 3 sub , the BrF sub 3 sub molecule ... de bromo ru III simple Bromine trifluoride zh ... more details
Ref chemboximage correct ?? ImageNameL1 Skeletal formula of chlorine trifluoride with some measurements ImageFileR1 Chlorine trifluoride 3D vdW.png ImageFileR1 Ref chemboximage correct ?? ImageNameR1 Spacefill model of chlorine trifluoride SystematicName Trifluoro sup 3 sup chlorane ref Cite web title chlorine trifluoride Compound Summary url http pubchem.ncbi.nlm.nih.gov summary summary.cgi?cid ... EINECS 232 230 4 UNNumber 1749 MeSHName chlorine trifluoride ChEBI 30123 ChEBI Ref ebicite correct ... trifluoride Cite web title chlorine trifluoride url http webbook.nist.gov cgi cbook.cgi?ID 7790 91 ... sup 1 sup mol sup 1 sup ref name chlorine trifluoride Section5 Chembox Hazards ExternalMSDS http natlex.ilo.ch ... Bromine trifluoride Chlorine trifluoride is an Interhalogen interhalogen compound with the formula ClF ... Trifluoride author Hitoshi Habuka, Takahiro Sukenobu, Hideyuki Koda, Takashi Takeuchi, and Masahiko ... Process for chlorine trifluoride chamber cleaning ref in nuclear reactor fuel processing, ref cite ... trifluoride burns glass. above this temperature it decomposes by a free radical mechanism to the elements ... trifluoride burned itself through 30 cm of concrete and 90 cm of gravel beneath. ref Air Products ... trifluoride must be carefully checked and cleaned, because any contamination can ignite on contact ... incapable of suppressing this oxidation or can aggravate it chlorine trifluoride has been reported ... amounts of chlorine trifluoride, as a liquid or as a gas, ignites tissue. The hydrolysis reaction with water ... trifluoride was investigated for military applications by the Kaiser Wilhelm Institute in Nazi ... germany 2004.htm Bunker Tours report on Falkenhagen ref Rocket propellant Chlorine trifluoride ... blockquote Semiconductor industry In the semiconductor industry, chlorine trifluoride is used to clean ... Trifluoride author Yu D Shishkov, A A Opalovskii journal Russian Chemical Reviews year 1960 ... of the Interhalogen Compounds. I. Chlorine Trifluoride at 120 C author Robinson D. Burbank, Frank ... more details
, E. M. Bingham Diethylaminosulfur Trifluoride Organic Syntheses, Coll. Vol. 6, p.440 Vol. 57, p.50 ... TRIFLUORIDE FLUOROMETHYL PHENYL SULFONE, A REAGENT FOR THE SYNTHESIS OF FLUOROALKENES ... trifluoride is more thermally robust. See also Ishikawa reagent References reflist Category ... more details
855370 6 ref br Arsenic trifluoride is used as fluorinating non metal chlorides to fluorides, in this respect .... Part XV. Arsenic trifluoride antimony pentafluoride, Edwards A. J., Sills R. J. C. J. Chem. Soc ... Arsenic Trifluoride Category Arsenic compounds Category Fluorides Category Fluorinating agents Category ... di arsenico ja ru simple Arsenic trifluoride ... more details
chembox verifiedrevid 464205508 Name Phosphorus trifluoride ImageFileL1 Phosphorus trifluoride 2D dimensions.png ImageSizeL1 130px ImageNameL1 Structure and dimensions of phosphorus trifluoride ImageFileR1 Phosphorus trifluoride 3D vdW.png ImageSizeR1 110px ImageNameR1 Space filling model of phosphorus trifluoride IUPACName Phosphorus trifluoride br Phosphorus III fluoride br Trifluorophosphane br Trifluoridophosphorus OtherNames Trifluorophosphine br Phosphorous fluoride Section1 Chembox Identifiers ChemSpiderID Ref chemspidercite correct chemspider ChemSpiderID 56416 InChI 1 F3P c1 4 2 3 InChIKey WKFBZNUBXWCCHG UHFFFAOYAK ChEBI Ref ebicite correct EBI ChEBI 30205 SMILES FP F F StdInChI Ref stdinchicite correct chemspider StdInChI 1S F3P c1 4 2 3 StdInChIKey Ref stdinchicite correct chemspider ... tribromide br Phosphorus triiodide OtherCations Nitrogen trifluoride br Arsenic trifluoride br Antimony trifluoride br Bismuth trifluoride Function ligand s OtherFunctn Carbon monoxide OtherCpds Phosphorus pentafluoride Phosphorus trifluoride formula Phosphorus P Fluorine F sub 3 sub , is a colorless ... monoxide. Physical properties Phophorus trifluoride has a bond angle of 107 . Gas eous PF sub 3 sub ... downfield of phosphoric acid H sub 3 sub PO sub 4 sub . Properties Phosphorus trifluoride Hydrolysis ... Studies of Metal Carbonyl Phosphorus Trifluoride Complexes journal Accounts of Chemical ... Phosphorus trifluoride is usually prepared from phosphorus trichloride via halogen exchange using various fluoride s such as hydrogen fluoride , calcium fluoride , arsenic trifluoride , antimony trifluoride , or zinc fluoride ref cite journal author Williams, A. A. Parry, R. W. Dess, H. title ... Trifluoride journal Inorganic Syntheses year 1990 volume 28 pages 310 315 doi 10.1002 9780470132593.ch77 ... 2 PF sub 3 sub 3 Zinc chloride ZnCl sub 2 sub Biological activity Phosphorus trifluoride is similar ... compounds DEFAULTSORT Phosphorus Trifluoride Category Inorganic phosphorus compounds Category Fluorides ... more details
chembox verifiedrevid 449910966 Name Nitrogen trifluoride ImageFile Nitrogen trifluoride 2D dimensions.png ImageSize ImageName Nitrogen trifluoride ImageFile1 Nitrogen trifluoride 3D vdW.png ImageSize1 ImageName1 Nitrogen trifluoride IUPACName Nitrogen trifluoride OtherNames Nitrogen fluoride br Trifluoramine ... of nitrogen trifluoride , J. Phys. Chem. 1967,71 2 , pp 359 360, doi 10.1021 j100861a022 ref Section7 ... trifluoride is the inorganic compound with the chemical formula formula NF sub 3 sub . This nitrogen ... in microelectronics . Applications Nitrogen trifluoride is used in the plasma etching of silicon wafers. Today nitrogen trifluoride is predominantly employed in the cleaning of the PECVD ... nitride and silicon oxide . Nitrogen trifluoride can be used as well with tungsten silicide , and tungsten ... chemistry environmentally friendly replacement for nitrogen trifluoride in the manufacture ... ref Nitrogen trifluoride is also used in hydrogen fluoride laser hydrogen fluoride and deuterium fluoride ... , as well as several plastics. Synthesis and reactivity Nitrogen trifluoride is a rare example ... Ruff prepared nitrogen trifluoride by the electrolysis of a molten mixture of ammonium fluoride and hydrogen ... and global warming potential of nitrogen trifluoride journal Geophysical Research Letters Geophys ... first W. T. year 2008 title Environmental and health risk analysis of nitrogen trifluoride chem NF ... trifluoride NF3 url http www.rmets.org activities awards scholarships sch 2.php publisher Royal Meteorological ... journal last Weiss first Ray F. coauthors J. M hle, P.K. Salameh, C.M. Harth title Nitrogen trifluoride ... trifluoride to the CO sub 2 sub budget of thin film solar cell production is compensated already within ... Hulbert, D.B. Cooper, P.J. Maroulis PJ title Life Cycle Nitrogen Trifluoride Emissions from Photovoltaics ... name gasworld08 cite web url http www.gasworld.com news.php?a 2896 title Nitrogen trifluoride Cleaning ... DEFAULTSORT Nitrogen Trifluoride Category Inorganic amines Category Fluorides Category Nitrogen halides ... more details
Chembox verifiedrevid 443393295 ImageFileL1 Antimony trifluoride 2D.png ImageNameL1 Structural formula ImageFileR1 Antimony trifluoride molecule in xtal 3D vdW.png ImageSizeR1 100px ImageNameR1 space filling model ImageFile2 Antimony trifluoride unit cell 1970 CM 3D ellipsoids.png ImageName2 Unit cell ImageSize2 180px PIN Antimony III fluoride SystematicName Trifluorostibane OtherNames Trifluoroantimony Section1 Chembox Identifiers InChI1 1 3FH.Sb h3 1H q 3 p 3 InChIKey1 GUNJVIDCYZYFGV DFZHHIFOAW CASNo 7783 56 4 PubChem 24554 PubChem Ref Pubchemcite ChemSpiderID 22960 ChemSpiderID Ref chemspidercite correct chemspider EINECS 232 009 2 UNNumber UN 2923 RTECS CC5150000 InChI 1S 3FH.Sb h3 1H q 3 p 3 InChIKey GUNJVIDCYZYFGV UHFFFAOYSA K StdInChI Ref stdinchicite correct chemspider StdInChI 1S 3FH.Sb h3 1H q 3 p 3 StdInChIKey Ref stdinchicite correct chemspider StdInChIKey GUNJVIDCYZYFGV UHFFFAOYSA K SMILES F Sb F F Section2 Chembox Properties Formula SbF sub 3 sub MolarMass 178.75 g mol Appearance light gray crystals Odor pungent Density 4.379 g cm sup 3 sup MeltingPt 292 C 565.15 K BoilingPt 376 C 649.15 K Solubility 385 g 100 mL 0 C br 443 g 100 mL 20 C br 562 g 100 mL 30 C Section3 Chembox Structure CrystalStruct Orthorhombic , Pearson symbol oS16 SpaceGroup Ama2, No. 40 Section7 Chembox Hazards MainHazards FlashPt Autoignition NFPA H 3 NFPA F 0 NFPA R 0 LD50 7000 mg kg Section8 Chembox Related OtherCpds antimony pentafluoride Antimony trifluoride is the inorganic compound with the formula SbF sub 3 sub . Sometimes called Swart s reagent , is one of two principal fluoride s of antimony , the other being SbF sub 5 sub . It appears as a white solid. As well as some industrial ... chloride compounds to fluoride s. The method involved treatment with antimony trifluoride with chlorine ... Antimony Trifluoride Category Antimony compounds Category Fluorides Category Fluorinating agents ... it Trifluoruro di antimonio ja ru III simple Antimony trifluoride zh ... more details
saved book title Boron subtitle An overview cover image Boron mNACTEC.jpg cover color Boron An overview Overview Boron Isotopes Isotopes of boron Miscellany Allotropes of boronBoron deficiency medicine Boron deficiency plant disorder Boron monoxide Boron oxide Boron trioxide Boron suboxide Boron nitride Boron neutron capture therapy Boronic acid Category Wikipedia books on chemical elements Category Boron Wikipedia books on elements ... more details
chembox verifiedrevid 444225508 ImageFileL1 Thiazyl trifluoride 2D dimensions.png ImageSizeL1 150px ImageFileR1 Thiazyl trifluoride 3D vdW.png ImageSizeR1 IUPACName OtherNames Section1 Chembox Identifiers ChemSpiderID Ref chemspidercite correct chemspider ChemSpiderID 123471 InChI 1 F3NS c1 5 2,3 4 InChIKey UQUPGRNSXINWBS UHFFFAOYAR StdInChI Ref stdinchicite correct chemspider StdInChI 1S F3NS c1 5 2,3 4 StdInChIKey Ref stdinchicite correct chemspider StdInChIKey UQUPGRNSXINWBS UHFFFAOYSA N CASNo 15930 75 3 PubChem 140008 ChEBI Ref ebicite correct EBI ChEBI 30507 SMILES FS F F N Section2 Chembox Properties Formula NSF sub 3 sub MolarMass 103.07 g mol sup 1 sup Appearance Density MeltingPt 72.6 C BoilingPt 27.1 C Solubility Thiazyl trifluoride is a chemical compound of nitrogen , sulfur , and fluorine , having the chemical formula formula NSF sub 3 sub . It exists as a stable, colourless gas, and is an important precursor to other sulfur nitrogen fluorine compounds. ref cite journal author Oskar Glemser and R diger Mews title Chemistry of Thiazyl Fluoride NSF and Thiazyl Trifluoride NSF sub 3 sub A Quarter Century of Sulfur Nitrogen Fluorine Chemistry year 1980 journal Angewandte Chemie International Edition in English Angew. Chem Int. Ed Engl. volume 19 issue 11 pages 883 899 doi 10.1002 anie.198008831 ref It has tetrahedral molecular geometry around the sulfur atom, and is regarded to be a prime example of a compound that has a sulfur nitrogen triple bond . ref cite doi 10.1016 j.ica.2007.05.016 ref NSF sub 3 sub can be synthesised by the fluorination of thiazyl fluoride , NSF, with silver II fluoride , AgF sub 2 sub NSF 2 AgF sub 2 sub NSF sub 3 sub 2 AgF It is also a product of the oxidation of ammonia by disulfur decafluoride chem S 2 F 10 . ref cite book title Biological interactions of sulfur compounds author Steve Mitchell editor Steve Mitchell publisher CRC Press year 1996 isbn 0748402454 page 14 ref References reflist Category Fluorides Category Nitrides Category ... more details
Boron monofluoride can be prepared by passing borontrifluoride gas at 2000 C over a boron ... Reactions BF can react with itself to form polymers of boron containing fluorine with between 10 and 14 boron atoms. BF reacts with borontrifluoride BF sub 3 sub to form Diboron tetrafluoride B sub ...Chembox OtherNames Boron fluoride br Boron I fluoride br Fluoroboronene br Fluoroborylene Section1 Chembox Identifiers CASNo 13768 60 0 PubChem 6336604 PubChem Ref Pubchemcite correct pubchem ChemSpiderID 4891729 ChemSpiderID Ref chemspidercite correct chemspider EINECS 237 383 0 SMILES B F StdInChI 1S BF c1 2 StdInChI Ref stdinchicite correct chemspider StdInChIKey YFSQMOVEGCCDJL UHFFFAOYSA N StdInChIKey Ref stdinchicite correct chemspider Section2 Chembox Properties B 1 F 1 ExactMass 30.007708671 g mol sup 1 sup Section3 Chembox Thermochemistry DeltaHf 115.90 kJ mol sup 1 sup Entropy 200.48 J K sup 1 sup mol sup 1 sup boron monofluoride or fluoroborylene is a chemical compound with formula BF, one atom of boron and one of fluorine . It was discovered as an unstable gas and only in 2009 found to be a stable ligand combining with transition metal s, in the same way as carbon monoxide . It is a subhalide, containing fewer than the normal number of fluorine atoms, compared with borontrifluoride . BF is isoelectronic with carbon monoxide and dinitrogen . Structure The experimental B F bond length is 1.263 angstrom . ref cite journal author Cazzoli, G. Cludi, L. Degli Esposti, C. Dore, L. title The millimeter and submillimeter wave spectrum of boron monofluoride Equilibrium structure journal Journal of Molecular Spectroscopy year 1989 volume 134 issue 1 pages 159 167 issn 0022 2852 doi 10.1016 0022 2852 89 90138 0 ref One reported computed bond order for the molecule is 1.4. ref ... Fe CO sub 5 sub , however this has not been reproduced. ref name bfmc References reflist Boron compounds Category Boron compounds Category Fluorides Category Ligands ... more details
chembox Watchedfields changed verifiedrevid 419956712 IUPACName Chromium III fluoride Othernames Chromium trifluoride ImageFile Aluminium trifluoride 3D polyhedra.png ImageSize 200px ImageFile2 FeF3structure.jpg ImageSize2 200px Section1 Chembox Identifiers ChemSpiderID Ref chemspidercite correct chemspider ChemSpiderID 8329529 InChI 1 Cr.3FH h 3 1H q 2 p 3 SMILES Cr 2 . F . F . F InChIKey FEQFRFOUOCAJNF DFZHHIFOAC InChI1 1 Cr.3FH h 3 1H q 3 p 3 InChIKey1 FTBATIJJKIIOTP DFZHHIFOAR SMILES1 Cr 3 . F . F . F StdInChI Ref stdinchicite correct chemspider StdInChI 1S Cr.3FH h 3 1H q 3 p 3 StdInChIKey Ref stdinchicite correct chemspider StdInChIKey FTBATIJJKIIOTP UHFFFAOYSA K CASNo Ref cascite correct ?? CASNo 7788 97 8 CASNo1 16671 27 5 CASNo1 Comment trihydrate CASNo2 123333 98 2 CASNo2 Comment tetrahydrate PubChem 10154021 RTECS GB6125000 Section2 Chembox Properties Formula CrF sub 3 sub MolarMass 108.9913 g mol anhydrous , 163.037 g mol trihydrate , 181.05 g mol tetrahydrate Appearance green crystalline solid Density 3.8 g cm sup 3 sup anhydrous , 2.2 g cm sup 3 sup trihydrate MeltingPt 1100 C sublimes Solubility negligible anhydrous , sparingly soluble trihydrate SolubleOther insoluble and alcohols br soluble in hydrofluoric acid HF , hydrochloric acid HCl Section3 Chembox Structure CrystalStruct Rhombohedral , Pearson symbol hR24 SpaceGroup R 3c, No. 167 Chromium III fluoride is the name for the inorganic compound s with the formula CrF sub 3 sub as well as several related hydrate s. The compound CrF sub 3 sub is a green crystalline solid that is insoluble in common solvents, but the coloured hydrates Cr H sub 2 sub O sub 6 sub F sub 3 sub and Cr H sub 2 sub O sub 6 sub F sub 3 sub sup . sup 3H sub 2 sub O are soluble in water. The trihydrate is green, and the hexahydrate is violet The anhydrous form sublimes at 1100 1200 C. Like almost all compounds of chromium III , these compounds feature octahedral molecular geometry octahedral Cr centres. In the anhydr ... more details
Wiktionarypar boronBoron is a chemical element. Boron can also refer to Boron, California , a census designated place in California Boron, Mali , a town and commune in Mali Boron, Territoire de Belfort , a commune d partement in France Kathrin Boron , German Olympic athlete Walter Boron , American scientist Robert de Boron , medieval poet Boron Oil, a subsidiary and brand of Standard Oil of Ohio , acquired by BP Boron Kingdom , a fictional alien race in the X computer game series Boron House of B or , a fictional character in J. R. R. Tolkien s Middle earth legendarium disambig de Boron fr Boron homonymie it Boron nl Boron ja pt Boron uk vo Boron ... more details
18 C Section8 Chembox Related OtherCpds Borontrifluoride br Boron trichloride br Boron triiodide Boron tribromide , BBr sub 3 sub , is a colorless, fuming liquid compound containing boron and bromine ...chembox verifiedrevid 399887121 Name Boron tribromide ImageFile Boron tribromide 3D vdW.png ImageSize 200px ImageName Boron tribromide IUPACName Boron tribromide OtherNames Tribromoborane Section1 Chembox Identifiers ChemSpiderID Ref chemspidercite correct chemspider ChemSpiderID 16787736 InChI 1 BBr3 c2 1 3 4 SMILES BrB Br Br InChIKey ILAHWRKJUDSMFH UHFFFAOYAA InChI1 1 B.3BrH h 3 1H q 3 p 3 InChIKey1 LKBREHQHCVRNFR DFZHHIFOAX SMILES1 BH6 3 . Br . Br . Br StdInChI Ref stdinchicite correct chemspider StdInChI 1S B.3BrH h 3 1H q 3 p 3 StdInChIKey Ref stdinchicite correct chemspider StdInChIKey LKBREHQHCVRNFR ... Chemicals title 132 BORON TRIBROMIDE ref Chemical properties Boron tribromide is commercially available ... . ref name doya cite journal title Boron Tribromide author Doyag ez, E. G. journal Synlett year ... industry uses boron tribromide as a boron source in pre deposition processes for doping ... 10.1016 j.solmat.2008.09.019 ref Synthesis The reaction of boron carbide with bromine at temperatures above 300 C leads to the formation of boron tribromide. The product can be purified by vacuum distillation . History The first synthesis was done by M. Poggiale in 1846 by reacting boron trioxide with carbon ... Claire Deville Deville in 1857. By starting from amorphous boron the reaction temperatures are lower ... reflist Further reading cite journal title Boron Tribromide author Doyag ez, E. G. journal Synlett ... https fscimage.fishersci.com msds 96654.htm title Material Safety Data Sheet Boron tribromide publisher Fisher Science cite patent country US status patent number 2989375 title Production of Boron Tribromide inventor May, F. H. Bradford, J. L. assign1 American Potash & Chemical gdate 1961 06 20 Boron compounds Category Boron compounds Category Bromides Category Nonmetal halides Category Boron halides ... more details
FlashPt 17 C NFPA H 4 NFPA F 0 NFPA R 2 NFPA O Section8 Chembox Related OtherAnions Borontrifluoride br Boron tribromide br Boron triiodide OtherCations Aluminium chloride br Gallium chloride OtherCpds Boron trioxide br Carbon tetrachloride Boron trichloride is a chemical compound with the formula ...chembox verifiedrevid 437566675 Name Boron trichloride ImageFile Boron trichloride 2D.png ImageSize 150px ImageName Boron trichloride ImageFile1 Boron trichloride 3D vdW.png ImageSize1 150px ImageName1 Boron trichloride IUPACName Boron trichloride OtherNames Boron III chloride Section1 Chembox Identifiers ... reactive. Production and properties Boron reacts with halogens to give the corresponding trihalides. Boron trichloride is, however, produced industrially by direct chlorination of boron oxide ... boron trihalides, and has a bond length of 175pm. It has a zero dipole moment because it is symmetric and therefore the dipole moments associated with the bonds cancel each other out. Boron trichloride ... temperatures 20 K . NMR studies of mixtures of boron trihalides shows the presence of mixed halides ..., W., Lappert, M. F. title Reactions Of Boron Trichloride With Organic Compounds journal Chemical Reviews ... 3 sub & x21CC CH sub 3 sub sub 2 sub S BCl sub 3 sub When boron trichloride is passed at low pressure ... are known to contain closed cages of boron atoms. The mixed aryl and alkyl boron chlorides are also of interest. Phenyl boron dichloride is commercially available. Such species can be prepared by the reaction ... 2 sub R sub 2 sub SnCl sub 2 sub Uses Boron trichloride is a starting material for the production of elemental boron. It is also used in the refining of aluminium , magnesium , zinc , and copper alloys ... the melt with boron trichloride vapors. In the manufacture of electrical resistors, a uniform ... used in the field of high energy fuels and rocket propellants as a source of boron to raise BTU value ... cite encyclopedia author Yamamoto, Y. Miyaura, N. title Boron Trichloride encyclopedia Encyclopedia ... more details
Boron deficiency may refer to Boron deficiency plant disorder , a nutritional disorder in plants Boron deficiency medicine , a nutritional disorder in animals disamb ... more details
Boron oxide may refer to Boron trioxide B sub 2 sub O sub 3 sub the most common form Boron monoxide B sub 2 sub O Boron suboxide B sub 6 sub O Category Boron compounds dab ... more details
this is achieved by adding hydrogen gas, borontrifluoride is used for c BN. Ion beam deposition ... correct ?? ImageSize 140 ImageName Magnified sample of crystalline hexagonal boron nitride IUPACName Boron nitride Section1 Chembox Identifiers CASNo 10043 11 5 CASNo Ref cascite correct CAS PubChem ... 0 NFPA R 0 RPhrases R36 37 SPhrases S26 , S36 Section8 Chembox Related OtherCpds Boron arsenide br Boron carbide br Boron phosphide br Boron trioxide Boron nitride is a chemical compound with chemical formula BN, consisting of equal numbers of boron and nitrogen atoms. BN is isoelectronic to a similarly ... and may even be harder than the cubic form. Boron nitride is not found in nature and is therefore produced synthetically from boric acid or boron trioxide . The initial product is amorphous ... of excellent thermal and chemical stability, boron nitride ceramics are traditionally used as parts of high temperature equipment. Boron nitride has a great potential in nanotechnology. Nanotubes ... stable than carbon nanotubes which favors them for some applications. Structure Boron nitride ... to graphite. Within each layer, boron and nitrogen atoms are bound by strong covalent bond s, whereas ... differs, however, from the pattern seen for graphite, because the atoms are eclipsed, with boron ... as lonsdaleite , a rare hexagonal polymorph of carbon. In both c BN and w BN boron and nitrogen ... center File Boron nitride hexagonal side 3D balls.png 250px center center File Boron nitride sphalerite 3D balls.png 200px center center File Boron nitride wurtzite 3D balls.png 200px center BN, hexagonal ... Relaxation Properties of Helium 3 Adsorbed on Hexagonal Boron Nitride journal Physical Review B volume ... Boron Nitride Thin Films year 1996 author R. Zedlitz journal Journal of Non Crystalline Solids ... X title Microstructure and Mechanical Properties of Pulsed Laser Deposited Boron Nitride Films ... of diamond and cubic boron nitride volume 2A2 doi 10.1007 b83029 isbn 978 3 540 42961 6 pages 118 ... more details
Unreferenced date December 2009 Orphan date December 2009 The total boron B sub T sub is the sum of boron species in a solution . In the environment these species usually include boric acid and borate , for example B sub T sub H sub 2 sub BO sub 3 sub sup &minus sup H sub 3 sub BO sub 3 sub where, B sub T sub is the total boron concentration br H sub 2 sub BO sub 3 sub sup &minus sup is the dihydrogen borate concentration br H sub 3 sub BO sub 3 sub is the boric acid concentration Total boron is an important quantity when determining alkalinity due to borate s contribution to a solution s acid neutraling capacity. Total boron is a conservative element in seawater, and can thus be calculated by simply knowing the salinity. See also Total organic carbon Alkalinity Total Alkalinity A sub T sub pH DEFAULTSORT Total Boron Category Chemical oceanography Category Analytical chemistry Category Boron ... more details
Chembox ImageFile ImageSize IUPACName Boronboron 3 Trinitrate trinitrate OtherNames Section1 Chembox Identifiers CASNo 71816 39 2 CASNo Ref cascite correct CAS PubChem ChemSpiderID 25934735 SMILES B 3 . N O O O . N O O O . N O O O InChI InChI 1S B.3NO3 c 3 2 1 3 4 q 3 3 1 Section2 Chembox Properties B 1 N 3 O 9 Appearance Density MeltingPt BoilingPt Solubility Section3 Chembox Hazards MainHazards FlashPt Autoignition Boron nitrate is a boron compound with the formula B NO sub 3 sub sub 3 sub . ref http www.quia.com jg 65767list.html Polyatomic Ionic Compounds ref References Reflist Boron compounds Category Boron compounds Category Nitrates inorganic compound stub ro Azotat de bor ... more details
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