Intersystemcrossing is a radiationless process involving a transition between two electronic states with different spin multiplicity . ref GoldBookRef title Intersystemcrossing file I03123 ref File Electronic Processes Involving Light.png thumb Excited electrons can undergo intersystemcrossing to a degenerate state with a different spin multiplicity. Singlet and triplet states When an electron in a molecule with a singlet ground state is excited via absorption of radiation to a higher energy level, either an excited singlet state or an excited triplet state will form. A singlet state is a molecular electronic state such that all Electron spin electron spins are paired. That is, the spin of the excited electron is still paired with the ground state electron a pair of electrons in the same energy level must have opposite spins, per the Pauli exclusion principle . In a triplet state the excited electron is no longer paired with the ground state electron that is, they are parallel same spin . Since excitation to a triplet state involves an additional forbidden spin transition, it is more probable that an excited singlet will form upon absorption of radiation. Image ISC excited states.png thumb 300 px right Singlet and triplet energy levels. When a singlet state nonradiatively transitions to a triplet state, or conversely a triplet transitions to a singlet, that process is known as intersystemcrossing. In essence, the spin of the excited electron is reversed. The probability of this process ... in such molecules are substantial and a change in spin is thus more favourable, intersystemcrossing ... enhances intersystemcrossing. ref Douglas A. Skoog, F. James Holler, and Timothy A. Nieman ... multiplicity is observed, phosphorescence is another manifestation of intersystemcrossing. The time scale of intersystemcrossing is on the order of 10 sup 8 sup to 10 sup 3 sup s, one of the slowest ... Rotational symmetry de IntersystemCrossing fr Conversion intersyst me it Incrocio intersistema ru ... more details
wiktionary crossingCrossing may refer to Entertainment Crossing album Crossing album , an album by world music jazz group Oregon Crossing 2005 film Crossing 2005 film , a Canadian independent feature film Crossing 2008 film Crossing 2008 film , a South Korean film Animal Crossing , a video game Other Crossing physics , the relation between particle and antiparticle scattering Crossing architecture , the junction of the four arms of a cruciform church River crossing disambiguation , any means to get from one riverbank to the other Border crossing Voice crossing , compositional technique Road crossing disambiguation , various types Sign of the Cross , or crossing oneself , a ritual hand motion made by members of many branches of Christianity See also Cross disambiguation Crossing the Line disambiguation Crossing the T Crossing the Rubicon disambiguation The Crossing disambiguation Global Crossing , communications company Intersection disambiguation , synonymous to crossing in many aspects lookfrom intitle disambig cs P ejezd es Cruce ja ru ... more details
The Crossing may refer to The Crossing Big Country album The Crossing Big Country album , 1983, and the title song The Crossing Church , a megachurch in Quincy, Illinois The Crossing Sanjay Mishra album The Crossing Sanjay Mishra album The Crossing Star Trek Enterprise The Crossing Star Trek Enterprise , an episode of the television series Star Trek Enterprise The Crossing The Twilight Zone The Crossing The Twilight Zone The Crossing 1990 film The Crossing 1990 film , a film starring Russell Crowe and Danielle Spencer The Crossing 2000 film The Crossing 2000 film , a 2000 A&E film based on the novel of the same name by Howard Fast starring Jeff Daniels as George Washington The Crossing 2010 film The Crossing 2010 film , a 2010 Turkish film The Crossing 2011 film , an upcoming film starring Megan Fox The Crossing novel The Crossing novel , a 1994 novel by prize winning American author Cormac McCarthy The Crossing Gary Paulsen novel The Crossing Gary Paulsen novel , a novel released in 1990 by Gary Paulsen The Crossing video game The Crossing video game , a first person shooter computer game by Arkane Studios The Crossing , a 1904 historical novel by Winston Churchill novelist Winston Churchill , a popular American writer, who later became a New Hampshire state legislator The Crossing, California , unincorporated community in Lassen County The Crossing choral ensemble , a professional choral ensemble directed by Donald Nally The west to east crossing of the Suez Canal by the Egyptian army at the start of the Yom Kippur War in 1973, known as Operation Badr 1973 Operation Badr See also Cross disambiguation disambiguation de The Crossing it The Crossing nl The Crossing ... more details
nofootnotes date September 2009 Image Crossing the T.gif thumb 250px right In this animation, the ship near the top is crossing the T of the ship on the bottom. Crossing the T or Capping the T is a classic naval warfare tactic attempted from the late 19th to mid 20th century, in which a line of warship s crossed in front of a line of enemy ships, allowing the crossing line to bring all their guns to bear while receiving fire from only the forward guns of the enemy. ref cite book title Fleet tactics and coastal combat last Hughes first Wayne P. authorlink coauthors year 2000 publisher Naval Institute Press location isbn 9781557503923 page 74 pages url accessdate ref It became possible to bring all of a ship s main guns to bear only in the late 19th and the early 20th centuries with the advent of steam powered battleships with rotating gun turrets, which were able to move faster and turn quicker than sailing ships, which had fixed guns facing sideways. The tactic became largely obsolete with the introduction of missile s and aircraft as long range strikes are not dependent on the direction the ships are facing. Tactics When going into battle, ships would assume a battle line formation called line astern , in which one vessel followed another in one or more parallel lines. This allowed each ship to fire over wide arcs without lofting salvo salvos of Shell projectile projectiles over friendly vessels. Each ship in the line generally engaged its opposite number in the enemy battle line which moved in a Parallel geometry parallel course. Image Crossing the T 1 Man ver.png thumb 200px right The blue ships are crossing the T of the red ships However, moving ahead of the enemy line on a perpendicular course crossing the T enabled a ship to launch salvoes at the same target with both ... critical for the ship doing the crossing, while simultaneously more critical for the ship being crossed ... url Category Naval warfare tactics Crossing the T Category Military terminology cs P ka T de Crossing ... more details
wikt Road crossing may refer to Railroad crossing or level crossing Pedestrian crossing Strand Road Crossing , a terminus in the United Kingdom See also lookfrom intitle Road disambiguation Crossing disambiguation Bike crossing disambiguation dab ... more details
Bike crossing may refer to Bicycle sharing system A road crossing in segregated cycle facilities See also Road crossing disambiguation Crossing disambiguation es Bike Crossing Spanish Wikipedia for Spanish philanthropic scheme http www.bike crossing.org disambig ... more details
Washington Crossing may refer to Places Washington s Crossing , the location in both New Jersey and Pennsylvania, a U.S. National Historic Landmark Washington Crossing State Park , Titusville, New Jersey Washington Crossing, Pennsylvania Washington Crossing Historic Park , Pennsylvania Washington Crossing Bridge A historical event Washington s crossing of the Delaware River , a famous American Revolutionary War event that took place on the night of December 25, 1776 Art and literature about the event Washington Crossing the Delaware , a painting commemorating the crossing Washington Crossing the Delaware sonnet Washington Crossing the Delaware sonnet , a sonnet by David Schulman about the scene in the painting Washington s Crossing book Washington s Crossing book , a book by David Hackett Fisher The Crossing 2000 film The Crossing 2000 film , an A&E television movie starring Jeff Daniels as George Washington disambig ... more details
Crossing sequence may refer to Crossing sequence signal , a sound pattern when a train crosses a level crossingCrossing sequence operation , a sequence of safety actions carried out when a train approeches and passes a level crossingCrossing sequence Turing machines disambig ... more details
A Grand crossing is a bridge or tunnel at a major water body. Grand Crossing may also refer to a place in the United States Grand Crossing, Florida Greater Grand Crossing, Chicago , Illinois the district surrounding Los Angeles Stadium Disambig ... more details
Crossing Over may refer to Chromosomal crossover , a cellular process Crossing Over album Crossing Over album , a 1998 album by Hesperus ensemble Hesperus Crossing Over , a book by John Edward Crossing Over film Crossing Over film , a 2009 film Crossing Over , a song by Five Finger Death Punch from the album War Is the Answer Crossing Over a season 4 episode of List of Eureka episodes Season 4 2010 2011 Eureka TV series John Edward Crossing Over with John Edward Crossing Over with John Edward , a television show on which self described psychic John Edward gives readings to audience members disambiguation de Crossing Over fr Crossing Over ... more details
Crossing the Line may refer to Crossing the Line 2006 film Crossing the Line 2006 film , a 2006 documentary by Daniel Gordon Crossing the Line 2002 film Crossing the Line 2002 film , a 2002 film by Graeme Clifford Crossing the Line 2008 film Crossing the Line 2008 film , a 2008 short by Peter Jackson and the first film made with the Red one camera Crossing the Line novel Crossing the Line novel , a 2004 novel by Karen Traviss Crossing the Line a 2009 novel by Gillian Philip Crossing the Line, The French Institute Alliance Fran aise s annual fall festival. Crossing the Line an action often taken by Lars Aarup The phrase crossing the line may refer to when a film or TV director breaks the 180 degree rule by accident or design during filmmaking a line crossing ceremony in a ship voyage. disambig fr Crossing the Line ... more details
Crossing number may refer to Crossing number knot theory of a knot is the minimal number of crossings in any knot diagram for the knot. The average crossing number is a variant of crossing number obtained from a three dimensional embedding of a knot by averaging over all two dimensional projections. Crossing number graph theory of a graph is the minimal number of edge intersections in any planar representation of the graph. mathdab hu Metsz si sz m egy rtelm s t lap ja ... more details
Delaware Crossing may refer to An event Washington s crossing of the Delaware River with the Continental Army prior to the Battle of Trenton on December 26, 1776 Washington Crossing the Delaware , an oil painting depicting the above A place Washington Crossing State Park , a state park of New Jersey Washington Crossing Historic Park , a state park of Pennsylvania Grinter Place , a house on the US National Register of Historic Places above the Kansas River in the Muncie neighborhood of Kansas City, Kansas. disambig ... more details
Wiktionary river crossing A river crossing is a means to get from one river bank to the other and may refer to A ford river A bridge A tunnel Any type of Ferry A cable ferry A reaction ferry A water taxi See also Category Crossings by river River crossing puzzle Crossing the River , a 1993 historical fiction novel by Caryl Phillips Crossing disambiguation Disambiguation ... more details
Border Crossing may refer to Border Crossing album , an album by saxophonist Mike Osborne . Border Crossing band , a UK hip hop collective musical group. Border Crossing novel , a 2001 novel by English author Pat Barker . Border control , the measures used by a country to monitor or regulate its borders. Border checkpoint , the actual place to cross a border. disambig ... more details
thumb left 120px Control panel at a Pelican crossing Image Green man uk.jpg thumb 200px Green man in the UK A Pelican crossing is a type of pedestrian crossing featuring a pair of poles each with a standard ... Orpington High Street.jpg thumb 200px Pedestrians using a Pelican crossing on a high street The name ... Pelican crossing originated in the United Kingdom , but similar traffic control devices are in use throughout the world. The term is also used in the Republic of Ireland . The pelican crossing was a relatively minor development of the X way crossing . This earlier crossing was largely identical to the pelican crossing, but instead of a green light for motorists, featured a white diagonal cross. The intention of this was to distinguish the crossing lights from any nearby junction standard traffic ... markings, the X way crossing became the pelican crossing. The Pelican crossing was the first definitive light controlled crossing for pedestrians in the UK, introduced in 1969, after the earlier failed experiment of the panda crossing . Previously only zebra crossing s had been used, which have warning ... side of the road to the pedestrian. A puffin crossing has the lights on the same side as the pedestrian a toucan crossing is a crossing for pedestrians and bicycle s a pegasus crossing allows horse riders to cross as well. Additionally, a Pelican crossing, as distinct from a pedestrian crossing clarify reason it is a type of pedestrian crossing date April 2012 , has the special feature that while the green man flashes to indicate that pedestrians may continue crossing but may not start to cross ... the road are one crossing, even when there is a central island, therefore traffic must wait for pedestrians who are crossing from the other side of the island. This rule is different to similar standard pedestrian crossings where each portion of the crossing is treated as a separate crossing. However ... longer intervals. A HAWK beacon , used experimentally in the USA with a standard pedestrian crossing ... more details
The Last Crossing is a novel by Canada Canadian writer Guy Vanderhaeghe . It was first published in 2002 by McClelland and Stewart . A rethinking of the genre of the western fiction western , The Last Crossing is a tale of interwoven lives and stories taking place in the last half of the 19th century, travelling from England to the United States and the Canadian west. Awards and nominations The Last Crossing was one of the selected books in the 2004 edition of Canada Reads , championed by musician Jim Cuddy . The Last Crossing eventually won the competition. Nominated, IMPAC Dublin Literary Award 2004 External links http www.mcclelland.com catalog display.pperl?isbn 0771087381 The Last Crossing at McClelland & Stewart http www.impacdublinaward.ie 2004 20Award Titles Vanderhaeghe.htm IMPAC Dublin Literary Award citation for The Last Crossing DEFAULTSORT Last Crossing, The Category 2002 novels Category Novels by Guy Vanderhaeghe Category Western genre novels Category Secret histories Category Novels set in the United States Category Novels set in England Category Novels set in Saskatchewan Category Canadian Western novels Category Canadian novels 2000s novel stub ... more details
Image TUCANCrossing.jpg thumb Toucan crossing No footnotes date November 2010 A toucan crossing is a type of pedestrian crossing found in the United Kingdom that also allows bicycle s to be ridden across. Since two can , both pedestrians and cyclists, cross together, the name toucan was chosen. File Colliers Wood London 2011 15.jpg thumb Toucan crossing signals Toucan crossings are normally 4 metres 13  feet wide, instead of the 2.8 metre 9  feet width of a pelican crossing or puffin crossing . A green bicycle is displayed next to the green man when cyclists and pedestrians are permitted to cross. Additionally, unlike the pelican crossing, before the lights for vehicles go back to green, a steady red and amber are displayed instead of a flashing amber. The pedestrian cyclist signal lights may be on the near side of the crossing like a puffin crossing , or on the opposite side of the road like a pelican crossing . Signalled cycle only crossings also exist, linking cycle tracks on opposite sides of the road. Cycles may be ridden or walked across, but not until the green cycle symbol is showing. ref The Highway Code , Rule 81 ref However, cycling across against a Red Cycle is not illegal, in contrast to cycling through a red light. Another variation on a toucan crossing is the pegasus crossing for horses and their riders. Notes Reflist References The History of British Roadsigns , Dept. for Transport, 2nd Edition, 1999 Pedestrian crossings DEFAULTSORT Toucan Crossing Category Cycling in the United Kingdom Category Pedestrian crossings Category Cycling safety Category Walking in the United Kingdom ... more details
File Pedestriancrossingaustralia.JPG thumb right A zebra crossing in Sydney , Australia File RaisedZebraCrossing Singapore 20070127.jpg thumb right A raised zebra crossing speed bump at a school zone in Marine ... to UK motorists that a pedestrian crossing is adjacent. It is an offence to stop a vehicle within the lines except when stopping at the crossing. File SchoolCrossing.jpg thumb right Crossing Guard at a school crossing in the US A zebra crossing is a type of pedestrian crossing used in many places ... surface, from which it derives its name. A zebra crossing typically gives extra Specify February 2012 date March 2012 rights of way traffic rights of way to pedestrians. Characteristics The crossing ... a light colour and a dark one. The similarity of these markings to those of a zebra give the crossing ..., pedestrians always have right of way traffic right of way on a zebra crossing. In countries such as the United ... countries they are also used on pedestrian crossing s controlled by traffic signals, and pedestrians ... History After isolated experiments, the zebra crossing was first used at 1000 sites in the UK in 1949 ... into law. In 1971, the Green Cross Code was introduced to teach children safer crossing habits, replacing the earlier kerb drill . In the United Kingdom the crossing is marked with Belisha beacon ... for visibility some 15 years later. Regional variations see also Pedestrian crossing Expand section date March 2009 In the United Kingdom, lollipop men or women crossing guards frequently attend zebra ... have right of way if they are still on the kerb but about to enter the zebra crossing. In North America ... to give way to pedestrians. If crossing the road within 20m of a zebra crossing pedestrians must use the crossing. Tiger crossing A tiger crossing is a variation used in the United Kingdom and Hong ..., but replaced them with toucan crossing s. ref name CrossingsMenagerie cite web author Cambridge Cycling ... the road. In popular culture File Abbey Road Zebra crossing 2004 01.jpg thumb 250px A zebra crossing ... more details
Refimprove date December 2009 Image Crossing.png thumb 250px Cathedral floor plan crossing is shaded A crossing , in church architecture ecclesiastical architecture , is the junction of the four arms of a cruciform cross shaped church. In a typically oriented church especially of Romanesque architecture Romanesque and Gothic architecture Gothic styles , the crossing gives access to the nave on the west, the transept arms on the north and south, and the quire architecture choir on the east. The crossing is sometimes surmounted by a tower or dome . A large crossing tower is particularly common on English Gothic architecture Gothic cathedrals. With the Renaissance , building a dome above the crossing became popular. Because the crossing is open on four sides, the weight of the tower or dome rests heavily on the corners a stable construction thus required great skill on the part of the builders. In centuries past, it was not uncommon for overly ambitious crossing towers to collapse. Sacrist Alan of Walsingham s octagon, built between 1322 and 1328 after the collapse of Ely s nave crossing on 22  February 1322, is the ... greatest individual achievement of architectural genius at Ely ... a lantern tower if it has openings through which light from outside can shine down to the crossing. In Early Medieval churches, the crossing square was often used as a module , or a unit of measurement. The nave and transept would have lengths that were a certain multiple of the length of the crossing ... tourlanterne.jpg Crossing and lantern tower, Rouen Cathedral Image Firenze duomoinside.jpg Crossing ... &c. engraved by J.LeKeux after a picture by G.Cattermole, 1821 edited.jpg Crossing tower, Canterbury Cathedral Image Notre dame paris top facing east.jpg Fl che above crossing, Notre Dame de Paris Image Toulouse Saint Sernin.jpg Crossing tower, Saint Sernin Basilica Image Plan Saint Sernin 2005 ... reflist refend Commons Crossing architecture DEFAULTSORT Crossing Architecture Category Church architecture ... more details
unreferenced date June 2010 A terrace crossing is a geographical zone between the sedimentation downstream part and the erosion upstream part of the river. This zone develops on the location where the transition of erosion to sedimentation takes place. Upstream of the crossing, Terrace geology terraces will exist. The highest terraces will be the oldest. Downstream of the crossing, older sediment sediments will be buried beneath younger Deposition geology deposits . See also Terrace geology Riverterrace Sedimentology Category Landforms Category Sedimentology Category Geomorphology nl Terrassenkruising ... more details
coord 39.1297200 96.4405551 display title Pillsbury Crossing is a natural limestone slab that was used by pioneers to cross Deep Creek. The ledge terminates in a waterfall in Riley County, Kansas , USA. The waterfall is about convert 40 ft m wide and has a drop of around convert 5 ft m . Below Pillsbury Crossing, Deep Creek flows into the Kansas River . The waterfall is named for Josiah Pillsbury, a Free Stater Free State settler in Kansas Territory who homesteaded by the crossing in 1855. Pillsbury was a member of the Free State Topeka Constitution Topeka Legislature and the failed Leavenworth Constitution al Convention. The site is part of Pillsbury Crossing Wildlife Area . References Manhattan Mercury , March 20, 2005 External links http www.kdwp.state.ks.us news KDWPT Info Locations Wildlife Areas Region 2 Pillsbury Crossing Pillsbury Crossing Wildlife Area official site http www.kansastravel.org pillsburycrossing.htm Deep Creek Waterfall at Pillsbury Crossing Wildlife Area Kansas Travel http www.kgs.ku.edu Extension KSplaces visit18.html Pilsbury Crossing Kansas Geological Survey Category Protected areas of Riley County, Kansas Category Landforms of Kansas Category Recreational areas in Kansas RileyCountyKS geo stub ... more details
Infobox Film name Brief Crossing image caption director Catherine Breillat producer eproducer aproducer writer Catherine Breillat starring Sarah Pratt br Gilles Guillain music cinematography Eric Gautier editing Pascale Chavance distributor released September 5, 2001 runtime country awards language budget gross preceded by followed by Brief Crossing Br ve travers e is a French language French film released in 2001 and directed by Catherine Breillat . It stars Sarah Pratt and Gilles Guillain . External links imdb title id 0299594 title Brief Crossing Catherine Breillat DEFAULTSORT Brief Crossing Category 2000s drama films Category 2001 films Category Films directed by Catherine Breillat Category French drama films Category French films fr Br ve travers e ... more details