An aldohexose is a hexose with an aldehyde group on one end.^[1][2]

The aldohexoses have four chiral centres for a total of 16 possible aldohexose stereoisomers (2⁴). Of these, only three commonly occur in nature: D-glucose, D-galactose, and D-mannose. The D/L configuration is based on the orientation of the hydroxyl at position 5, and does not refer to the direction of optical activity.

There are eight D-aldohexoses: <gallery> File:DAllose Fischer.svg | D-Allose File:DAltrose Fischer.svg | D-Altrose File:DGlucose Fischer.svg | D-Glucose File:Mannose.svg | D-Mannose File:DGulose Fischer.svg | D-Gulose File:DIdose Fischer.svg | D-Idose File:DGalactose Fischer.svg | D-Galactose File:DTalose Fischer.svg | D-Talose </gallery>

The chemist Emil Fischer is said to have devised the following mnemonic device for remembering the order given above, which corresponds to the configurations about the chiral centers when ordered as 3-bit binary strings: All altruists gladly make gum in gallon tanks.

Deoxyaldohexoses

Aldohexoses can have one or more of their hydroxyl groups replaced by hydrogens to form deoxyaldohexoses. The following are well known cases of such compounds :

• L-Fucose (6-deoxy-L-galactose)
• L-Rhamnose (6-deoxy-L-mannose)
• D-Quinovose (6-deoxy-D-glucose) - found as part of the sulfolipid SQDG.
• L-Pneumose (6-deoxy-L-talose)

References

ca:Aldohexosa de:Hexosen fr:Aldohexose hu:Aldohex z pt:Aldo-hexose sr:Aldoheksoza sv:Aldohexos zh: